American Chemical Society
am7b18650_si_001.pdf (1.6 MB)

Multivariate MOF-Templated Pomegranate-Like Ni/C as Efficient Bifunctional Electrocatalyst for Hydrogen Evolution and Urea Oxidation

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journal contribution
posted on 2018-01-08, 00:00 authored by Lu Wang, Lantian Ren, Xiaorui Wang, Xiao Feng, Junwen Zhou, Bo Wang
The production of hydrogen through electrolysis is considered as a feasible strategy to quench the world’s clean-energy thirst. Compared with water electrolysis, urea electrolysis presents a more promising prospect in the way that it could carry out sewage treatment as well as energy-efficient hydrogen production at the same time. Herein, highly porous pomegranate-like Ni/C was synthesized from multivariate metal–organic frameworks and exhibits excellent hydrogen evolution activity with an unprecedented low overpotential of 40 mV at the current density of 10 mA cm–2 in 1 M KOH, ranking among the best earth-abundant electrocatalysts deposited on glassy carbon electrodes reported to date. In addition, it also displays superb anodic urea oxidation activity with an onset potential of 1.33 V vs RHE. Furthermore, a two-electrode urea electrolyzer with Ni/C as both the cathode and anode electrocatalyst was fabricated and generates 52 times more hydrogen than the water electrolyzer under the same conditions.