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Morphology Dynamics of Single-Layered Ni(OH)2/NiOOH Nanosheets and Subsequent Fe Incorporation Studied by in Situ Electrochemical Atomic Force Microscopy

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journal contribution
posted on 09.10.2017, 00:00 by Jiang Deng, Michael R. Nellist, Michaela Burke Stevens, Christian Dette, Yong Wang, Shannon W. Boettcher
Nickel (oxy)­hydroxide-based (NiOxHy) materials are widely used for energy storage and conversion devices. Understanding dynamic processes at the solid–liquid interface of nickel (oxy)­hydroxide is important to improve reaction kinetics and efficiencies. In this study, in situ electrochemical atomic force microscopy (EC-AFM) was used to directly investigate dynamic changes of single-layered Ni­(OH)2 nanosheets during electrochemistry measurements. Reconstruction of Ni­(OH)2 nanosheets, along with insertion of ions from the electrolyte, results in an increase of the volume by 56% and redox capacity by 300%. We also directly observe Fe cations adsorb and integrate heterogeneously into or onto the nanosheets as a function of applied potential, further increasing apparent volume. Our findings are important for the fundamental understanding of NiOxHy-based supercapacitors and oxygen-evolution catalysts, illustrating the dynamic nature of Ni-based nanostructures under electrochemical conditions.

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