Monoimine Derived from trans-1,2-Diaminocyclohexane and Ethyl Glyoxylate: An Intermediate in Aza-Diels–Alder and Mannich Reactions

Wojaczyńska, Elżbieta; Bąkowicz, Julia; Dorsz, Mateusz; Skarżewski, Jacek

doi:10.1021/jo302820m.s001

Monoimine Derived from trans-1,2-Diaminocyclohexane and Ethyl Glyoxylate: An Intermediate in Aza-Diels–Alder and Mannich Reactions

https://doi.org/10.1021/jo302820m.s001
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posted on 2013-03-15, 00:00 authored by Elżbieta Wojaczyńska, Julia Bąkowicz, Mateusz Dorsz, Jacek Skarżewski

Novel enantiopure policyclic nitrogen heterocycles have been obtained in the diastereoselective aza-Diels–Alder or Mannich reaction of dienes with imine formed in situ from ethyl glyoxylate and (1R,2R)-diaminocyclohexane.

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DOI - Is supplement to Monoimine Derived from trans-1,2-Diaminocyclohexane and Ethyl Glyoxylate: An Intermediate in Aza-Diels–Alder and Mannich Reactions

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diastereoselective diene Intermediate Mannich ReactionsNovel enantiopure policyclic nitrogen heterocycles Mannich reaction Ethyl Glyoxylate Monoimine Derived ethyl glyoxylate tran

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Monoimine Derived from <i>trans</i>-1,2-Diaminocyclohexane and Ethyl Glyoxylate: An Intermediate in Aza-Diels–Alder and Mannich Reactions

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