ol6b02789_si_001.pdf (2.54 MB)
Mono- and Dihydroxylated Symmetrical Octamethylcucurbiturils and Allylated Derivatives
journal contribution
posted on 2016-10-21, 18:23 authored by Fang-Fang Shen, Kai Chen, Yun-Qian Zhang, Qian-Jiang Zhu, Zhu Tao, Hang CongMono- and dihydroxylated symmetrical
octamethylcucurbit[6]urils
{(OH)OMeQ[6] and (OH)2OMeQ[6]} were prepared using a photochemical
method to introduce limited alcohol group(s) directly to the parent
symmetrical octamethylcucurbit[6]uril (OMeQ[6]), and the resulting
compounds were verified by 1H NMR, Xevo Q-TOF MS, and X-ray
crystallography. Further chemical modification of mono- and dihydroxylated
OMeQ[6] was also performed.