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Download fileMolecular Nanoscale Magnetic Refrigerants: A Ferrimagnetic {CuII15GdIII7} Cagelike Cluster from the Use of Pyridine-2,6-dimethanol
journal contribution
posted on 16.09.2013, 00:00 authored by Despina Dermitzaki, Giulia Lorusso, Catherine
P. Raptopoulou, Vassilis Psycharis, Albert Escuer, Marco Evangelisti, Spyros P. Perlepes, Theocharis C. StamatatosThe employment of pyridine-2,6-dimethanol
in 3d/4f metal cluster
chemistry has afforded a new {CuII15GdIII7} cagelike molecule with a beautiful structure built
by fused triangular subunits; the compound exhibits an overall ferrimagnetic
behavior with an appreciable ground-state spin value and shows promise
as a low-temperature magnetic refrigerant.