MoS₂ Decoration Followed by P Inclusion over Ni-Co Bimetallic Metal–Organic Framework-Derived Heterostructures for Water Splitting

Demonstrating a highly efficient non-noble bifunctional catalyst for complete water electrolysis remains challenging because of kinetic limitations and crucial importance for future energy harvesting. Herein, a low-cost, integrated composite of a Ni–Co metal–organic framework decorated with thin MoS₂ nanosheets was synthesized by a simple hydrothermal method followed by carbonization and phosphorization for electrochemical oxygen and hydrogen evolution reactions. Such a composite heterostructure exhibits outstanding performance in the electrocatalysis process with a lower overpotential of 184 mV for the oxygen evolution reaction (OER) and 84 mV for the hydrogen evolution reaction (HER) in 1.0 M KOH and 0.5 M H₂SO₄ electrolytes to reach a current density of 10 mA cm^–2, with a slight Tafel slope of 63 mV dec^–1 for the OER and 96 mV dec^–1 for the HER. The obtained results are far better than those of the commercial benchmark catalyst. Furthermore, online gas chromatography quantifies the amount of hydrogen generation in a symmetric cell as equal to 0.002121 moles with an energy efficiency of about 2.237 mg/kWh. Thus, the composite electrode’s remarkable performance is further demonstrated as a potentially viable alternative non-noble electrocatalyst for energy conversion reactions.