posted on 2021-08-11, 13:34authored byMinu Kim, Steffen Klenner, Graham M. McNally, Jürgen Nuss, Alexander Yaresko, Ulrich Wedig, Reinhard K. Kremer, Rainer Pöttgen, Hidenori Takagi
Herein, we present
results of the 121Sb Mössbauer
spectroscopy in perovskite antimonates Ba1–xKxSbO3, sibling compounds
of the well-known high-Tc superconductors
Ba1–xKxBiO3. Two Sb valence states SbIII and SbV, forming a charge-density-wave (CDW) order, are unambiguously
revealed in un- and under-doped phases at x = 0–0.5.
As the CDW order is suppressed at x = 0.65, the compound
becomes superconducting and all of the Sb sites become equivalent
with the intermediate valence of +4.65, consistent with that anticipated
from the potassium content. These results provide the direct evidence
of metal s electrons participating in the formation of the CDW order
and superconductivity in the material, and thus they have important
implications for clarifying the underlying mechanism related to mixed
valence and potential valence fluctuations of metal ions. The use
of Mössbauer active nuclei offers a deeper insight into the
structural properties and superconductivity in mixed-valence main-group
oxides.