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Mild Synthesis of Organophosphorus Compounds:  Reaction of Phosphorus-Containing Carbenoids with Organoboranes

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journal contribution
posted on 06.03.2008, 00:00 by Monika I. Antczak, Jean-Luc Montchamp
Organoboranes react with phosphorus-containing carbenoids to produce a variety of functionalized organophosphorus compounds under mild conditions. In some cases, selective migration of one group attached to boron can be observed. Phosphonite−borane complexes are introduced as novel synthons for the synthesis of phosphinic esters.