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Metal–Organic Frameworks as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs

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journal contribution
posted on 03.06.2019, 00:00 by Hatem M. Titi, Mihails Arhangelskis, Athanassios D. Katsenis, Cristina Mottillo, Ghada Ayoub, Jean-Louis Do, Athena M. Fidelli, Robin D. Rogers, Tomislav Friščić
Systematic investigation of combustion energies for popular metal–organic framework materials reveals energy content comparable to conventional energetic materials, which can be further modified and fine-tuned through the control of framework topology or isostructural ligand replacement to yield energy densities comparable to conventional energetic materials such as trinitrotoluene and hydrazine-, diesel-, or kerosene-based fuels.