ol049038x_si_001.pdf (252.46 kB)
Download file

Memory of Chirality in the Transannular Cyclization of Cyclodecenyl Radicals

Download (252.46 kB)
journal contribution
posted on 05.08.2004, 00:00 by Jackline E. Dalgard, Scott D. Rychnovsky
The transannular cyclization of an enantioenriched cyclodecenyl radical proceeds in a 5-exo fashion to produce scalemic bicyclo[5.3.0]decanes. This cyclization is notable because it demonstrates chirality transfer through conformational memory of an unstabilized secondary radical.