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Magnetoelectric Coupling Induced Orbital Reconstruction and Ferromagnetic Insulating State in PbZr0.52Ti0.48O3/La0.67Sr0.33MnO3 Heterostructures

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journal contribution
posted on 27.07.2020, 14:04 authored by Chao Liu, Bangmin Zhang, Xiaoqian Yu, Xiaohan Wu, Pingfan Chen, Ping Yang, Xiaojiang Yu, Jun Ding, Jingsheng Chen, Gan Moog Chow
Novel phenomena at the ferromagnetic/ferroelectric interface have generated much interest. Here, a ferromagnetic insulating state with the Curie temperature about 268–286 K in PbZr0.52Ti0.48O3/La0.67Sr0.33MnO3 heterostructures is induced and modulated by varying the PbZr0.52Ti0.48O3 thickness. An abnormally enlarged c/a ratio in La0.67Sr0.33MnO3 by strain-based coupling effect leads to d3z2−r2 orbital preferable occupancy. This orbital reconstruction modulates effective electron transfer and finally leads to a ferromagnetic insulating state. Valence change induced by charge-based coupling effect could be partially responsible for change in the Curie temperature in the strongly correlated electron system of La1–xSrxMnO3. This work provides a deeper understanding of strain effects near the ferromagnetic/ferroelectric interface, especially in a PbZr1–yTiyO3/La1–xSrxMnO3 heterostructure system.