ol801478y_si_001.pdf (1.43 MB)

Magnetically Separable Pd Catalyst for Carbonylative Sonogashira Coupling Reactions for the Synthesis of α,β-Alkynyl Ketones

Download (1.43 MB)
journal contribution
posted on 18.09.2008, 00:00 by Jianming Liu, Xingao Peng, Wei Sun, Yongwei Zhao, Chungu Xia
A magnetically separable palladium catalyst was simply synthesized through a wet impregnation incorporating palladium nanoparticles and superparamagnetic Fe3O4 nanoparticles in KBH4 solution, which is a highly efficient catalyst for the carbonylative Sonogashira coupling reaction of aryl iodides with terminal alkynes under phosphine-free conditions. This catalyst is completely magnetically recoverable due to the super paramagnetic behavior of Fe3O4 and can be reused with sustained selectivity and activity.

History