nl0c01146_si_001.pdf (354.48 kB)

Long-Range Rhombohedral-Stacked Graphene through Shear

Download (354.48 kB)
journal contribution
posted on 17.06.2020, 14:51 by Jean Paul Nery, Matteo Calandra, Francesco Mauri
The discovery of superconductivity and correlated electronic states in the flat bands of twisted bilayer graphene has raised a lot of excitement. Flat bands also occur in multilayer graphene flakes that present rhombohedral (ABC) stacking order on many consecutive layers. Although Bernal-stacked (AB) graphene is more stable, long-range ABC-ordered flakes involving up to 50 layers have been surprisingly observed in natural samples. Here, we present a microscopic atomistic model, based on first-principles density functional theory calculations, that demonstrates how shear stress can produce long-range ABC order. A stress-angle phase diagram shows under which conditions ABC-stacked graphene can be obtained, providing an experimental guide for its synthesis.