Ketone-Catalyzed Decomposition of Peroxynitrite via Dioxirane
Intermediates

Yang, Dan; Tang, Yeung-Chiu; Chen, Jian; Wang, Xue-Chao; Bartberger, Michael D.; Houk, K. N.; Olson, Leif

doi:10.1021/ja984358v.s001

ja984358v_si_001.pdf (89.84 kB)

Ketone-Catalyzed Decomposition of Peroxynitrite via Dioxirane Intermediates

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posted on 1999-12-09, 00:00 authored by Dan Yang, Yeung-Chiu Tang, Jian Chen, Xue-Chao Wang, Michael D. Bartberger, K. N. Houk, Leif Olson

Ketones are found to be catalysts for the decomposition of peroxynitrite. Kinetics, product studies, and B3LYP transition-state calculations together provide consistent evidence for a mechanism involving the formation of dioxirane intermediates.

Ketone-Catalyzed Decomposition of Peroxynitrite via Dioxirane Intermediates

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