jo300929a_si_001.pdf (3.39 MB)

Julia–Kocienski Reaction-Based 1,3-Diene Synthesis: Aldehyde-Dependent (E,E/E,Z)-Selectivity

Download (3.39 MB)
journal contribution
posted on 20.07.2012, 00:00 by François Billard, Raphaël Robiette, Jiří Pospíšil
A new modification of Julia–Kocienski olefination reaction based on the use of cation-specific chelating agents that yields 1,3-dienes with predictable (E/Z)-selectivity on newly created double bond was developed. The influence of the aldehyde structure on reaction (E/Z) selectivity is discussed and rationalized.

History

Exports