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Iron-Catalyzed Grignard Cross-Coupling with Alkyl Halides Possessing β-Hydrogens

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journal contribution
posted on 15.04.2004, 00:00 by Takashi Nagano, Tamio Hayashi
Tris(acetylacetonato)iron(III) (Fe(acac)3) was found to be an efficient catalyst for the cross-coupling reaction between aryl Grignard reagents and alkyl halides possessing β-hydrogens. The reaction is applicable to secondary alkyl halides as well as primary ones.