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Iron-Catalyzed, Markovnikov-Selective Hydroboration of Styrenes

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journal contribution
posted on 21.02.2017, 16:35 by Xu Chen, Zhaoyang Cheng, Zhan Lu
A highly Markovnikov-selective, iron-catalyzed hydroboration of styrenes is reported using available oxazolinylphenyl picolinamide as the ligand to afford the branched hydroboration products with up to >50/1 b/l. This reaction is operationally simple and could be carried out in gram scale.

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