ol7b00227_si_001.pdf (4.6 MB)

Iron-Catalyzed, Markovnikov-Selective Hydroboration of Styrenes

Download (4.6 MB)
journal contribution
posted on 21.02.2017, 16:35 by Xu Chen, Zhaoyang Cheng, Zhan Lu
A highly Markovnikov-selective, iron-catalyzed hydroboration of styrenes is reported using available oxazolinylphenyl picolinamide as the ligand to afford the branched hydroboration products with up to >50/1 b/l. This reaction is operationally simple and could be carried out in gram scale.