Ionic Hydrogenation of Acylferrocenes Using Zinc Borohydride: An Efficient, Mild Method for the Preparation of Alkylferrocenes
journal contributionposted on 06.02.1996, 00:00 by Sukanta Bhattacharyya
An effective mild procedure for the reductive deoxygenation of α-ferrocenyl aldehydes, ketones, and alcohols into the corresponding alkylferrocenes is described using a combination of zinc borohydride and zinc chloride. This is the first example of such reactivity of zinc borohydride. The present method allows the synthesis of alkylferrocenes bearing terminally functionalized pendant chains.