Intermolecular Rhodium(II)-Catalyzed
Reactions with Silicon-Substituted
Carbonyl Ylides

Bolm, Carsten; Saladin, Sandra; Kasyan, Andrey

doi:10.1021/ol026987m.s001

ol026987m_si_001.pdf (68.63 kB)

Intermolecular Rhodium(II)-Catalyzed Reactions with Silicon-Substituted Carbonyl Ylides

journal contribution

posted on 2002-12-06, 00:00 authored by Carsten Bolm, Sandra Saladin, Andrey Kasyan

The Rh(II)-catalyzed reaction of benzyl 2-trialkylsilyl-2-diazoacetates with various acyclic and cyclic ketones affords novel dioxolanones via silicon-substituted carbonyl ylides in up to 98% yield.

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Keywords

carbonyl novel dioxolanones Rh Rhodium Ylide cyclic ketones trialkylsilyl ylide benzyl Carbonyl acyclic Intermolecular

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