American Chemical Society
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Intermolecular Rhodium(II)-Catalyzed Reactions with Silicon-Substituted Carbonyl Ylides

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journal contribution
posted on 2002-12-06, 00:00 authored by Carsten Bolm, Sandra Saladin, Andrey Kasyan
The Rh(II)-catalyzed reaction of benzyl 2-trialkylsilyl-2-diazoacetates with various acyclic and cyclic ketones affords novel dioxolanones via silicon-substituted carbonyl ylides in up to 98% yield.