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Intermetallic Compounds with 1D Infinite Tunnels. Syntheses and Structures of AAu4In2 (A = K, Rb)

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journal contribution
posted on 27.09.2006, 00:00 by Bin Li, John D. Corbett
Four intermetallic compounds KxRb1-xAu4In2 (x = 0−1) synthesized by high-temperature solid-state reactions display 1D infinite tunnel constructions with Au−In frameworks. These compounds show small but different cation displacements in the tunnels and are also air and moisture inert at room temperature, even in concentrated HCl(aq).