Interlayer Spacing Regulation of NiCo-LDH Nanosheets with Ultrahigh Specific Capacity for Battery-Type Supercapacitors

The transition metal-based layered double hydroxides (LDHs) have been extensively studied as promising functional nanomaterials owing to their excellent electrochemical activity and tunable chemical composition. In this work, using acetate anions (Ac^–) as intercalating elements, the NiCo-LDH nanosheets arraying on Ni foam with different amounts of Ac^– anion intercalation or volume of hydrothermal solution were prepared by a simple hydrothermal method. The optimized amount of Ac^– anions expanded the interlayer space of LDH nanosheets from 0.8 to 0.94 nm. An ultrahigh specific capacity of 1200 C g^–1 at 1 A g^–1 (690 C g^–1 without Ac^– anions), an outstanding rate capability of 72.5% at 30 A g^–1, and a cycle stability of 79.90% after 4500 cycles were mainly attributed to the higher interlayer spacing of Ac^– anion intercalation. The enlarged interlayer spacing was beneficial for stabilizing the α-phase of LDHs and accelerating the electron transport and electrolyte penetration in the electrochemical reaction. This work sheds light on the mechanisms of the interlayer spacing regulation of NiCo-LDH nanosheets and offers a promising strategy to synthesize functional nanomaterials with excellent electrochemical performance via integrating their unique layered structure and interlayer anion exchange characteristics.