posted on 2022-12-13, 21:04authored byRuobin Dai, Jiansuxuan Chen, Hongyi Han, Huimin Zhou, Zhiwei Wang
Polymeric membranes, which are typically synthesized
from fossil-based
polymers, will reach their end of life (EOL) and then be replaced,
due to the inevitable accumulation of membrane fouling even though
the periodic cleaning is applied. The conventional disposal methods
of the EOL membranes are landfilling and incineration, which will
lead to additional carbon emission and fossil resource depletion.
Herein, we proposed a surfactant-regulated interfacial polymerization
strategy, by adding sodium dodecylbenzene sulfonate (SDBS) in the
piperazine (PIP) aqueous solution, for the one-step upcycling of the
EOL polymeric microfiltration membrane to obtain a thin-film composite
polyamide (PA) nanofiltration (NF) membrane. Revealed by the quartz
crystal microbalance with dissipation analysis and molecular dynamics
simulation, the presence of SDBS reduced interfacial tension (IFT)
and regulated interfacial wettability, thereby facilitating adequate
and uniform uptake of PIP monomers. The resulting upcycled NF membrane
with 4 critical micelle concentration (CMC) of SDBS addition exhibited
a favorable pure water permeance (20.1 ± 0.6 L m–2 h–1 bar–1) and a satisfactory
Na2SO4 rejection of 98.6 ± 0.4% owing to
the formation of a continuous PA layer with high cross-linking degree
(89.3 ± 0.5%). The Na2SO4 permeability
of the 4 CMC upcycled NF membrane was more than 1 magnitude lower
than that of the upcycled NF membrane without SDBS addition. This
study provides a facile, rapid, and cost-effective method for the
one-step upcycling of EOL polymeric membranes, which thus improves
the sustainability of membrane technology.