Insights into Molecular Magnetism in Metal–Metal Bonded Systems as Revealed by a Spectroscopic and Computational Analysis of Diiron Complexes
journal contributionposted on 30.11.2020, 19:09 authored by Samuel M. Greer, Kathryn M. Gramigna, Christine M. Thomas, Sebastian A. Stoian, Stephen Hill
A pair of bimetallic compounds featuring Fe–Fe bonds, [Fe(iPrNPPh2)3FeR] (R = PMe3, NtBu), have been investigated using High-Frequency Electron Paramagnetic Resonance (HFEPR) as well as field- and temperature-dependent 57Fe nuclear γ resonance (Mössbauer) spectroscopy. To gain insight into the local site electronic structure, we have concurrently studied a compound containing a single Fe(II) in a geometry analogous to that of one of the dimer sites. Our spectroscopic studies have allowed for the assessment of the electronic structure via the determination of the zero-field splitting and 57Fe hyperfine parameters for the entire series. We also report on our efforts to correlate structure with physical properties in metal–metal bonded systems using ligand field theory guided by quantum chemical calculations. Through the insight gained in this study, we discuss strategies for the design of single-molecule magnets based on polymetallic compounds linked via direct metal–metal bonds.
Read the peer-reviewed publication
bimetallic compoundsspectroscopic studies3 FeRPMe 3polymetallic compoundsbondComputational AnalysisDiiron Complexestemperature-dependent 57 Fezero-field splitting57 Feligand field theoryHigh-Frequency Electron Paramagneti...quantum chemical calculationsgain insightγ resonanceHFEPRsingle-molecule magnetsdimer sitesMolecular Magnetism