American Chemical Society
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Inorganic Quadricyclanes:  Synthesis and Characterization of Novel Sulfur- and Selenium-Bridged Mixed Cr/Fe Clusters, CrFe2(CO)10E4 (E = S, Se). Crystal Structure of CrFe2(CO)10Se4

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journal contribution
posted on 1997-01-07, 00:00 authored by Pradeep Mathur, P. Sekar, Arnold L. Rheingold, Louise M. Liable-Sands
The new clusters CrFe2(CO)10E4 (E = S, 1; E = Se, 2) have been isolated from the room-temperature reactions of Fe2(CO)6(μ-E2) and Cr(CO)5(THF), and the structure of CrFe2(CO)10Se4has been established by single-crystal X-ray diffraction methods.