ol4005257_si_001.pdf (1.16 MB)
Download file

Indium(III) Halide-Catalyzed UV-Irradiated Radical Coupling of Iodomethylphosphorus Compounds with Various Organostannanes

Download (1.16 MB)
journal contribution
posted on 2016-02-19, 13:40 authored by Itaru Suzuki, Kensuke Kiyokawa, Makoto Yasuda, Akio Baba
The first catalytic radical coupling of iodomethylphosphorus compounds was accomplished with allyl-, alkenyl-, and allenylstannanes under UV irradiation in the presence of an indium(III) halide catalyst, for which a transmetalated allylic indium species was confirmed to be an active radical species.