cg9b01697_si_001.pdf (2.57 MB)
Incorporation of Clathrochelate-Based Metalloligands in Metal–Organic Frameworks by Solvent-Assisted Ligand Exchange
journal contributionposted on 2020-02-13, 20:35 authored by Ophélie M. Planes, Pascal A. Schouwink, José L. Bila, Farzaneh Fadaei-Tirani, Rosario Scopelliti, Kay Severin
Iron(II) cage complexes with terminal 4-pyridyl groups can be incorporated in metal–organic frameworks (MOFs) via solvent-assisted ligand exchange (SALE). Paddle-wheeled MOFs with N,N′-di-4-pyridylnaphthalenetetracarboxydiimide pillars were used as starting materials. Pillar exchange was nearly quantitative, despite the fact that the cage complexes are long (∼15 Å) and sterically demanding. The reactions provide products of high crystallinity, and the structures of daughter MOFs were determined by single crystal X-ray diffraction. The crystallographic analyses showed that some of the SALE experiments led to topological changes of the MOF structures.