posted on 2016-02-18, 21:30authored byRosa Martín-Rodríguez, Robin Geitenbeek, Andries Meijerink
Doping
quantum dots (QDs) with lanthanide ions is promising to
combine the efficient sharp line emission of lanthanides with the
strong and size-tunable absorption of QDs. Incorporating lanthanide
ions in II–VI QDs remains challenging, however, here we report
successful coupling of CdSe QDs with the lanthanide ion Yb3+. Our spectroscopic results demonstrate that Yb3+ ions
are first adsorbed on the CdSe surface and subsequently incorporated
in the nanocrystalline semiconductor particles by growing a Se shell.
Evidence for incorporation is provided by the fine structure of the
CdSe QDs absorption in the excitation spectrum of the Yb3+ emission at 1000 nm and the long lifetime of the Yb3+ emission after shell overgrowth. Sensitized Yb3+ infrared
emission may find application in optical amplifiers, solar concentrators,
and bioimaging. The method described is a promising strategy for incorporating
lanthanide ions in other II–VI QDs.