ol015819b_si_001.pdf (83.58 kB)
In Situ Oxidation−Imine Formation−Reduction Routes from Alcohols to Amines
journal contributionposted on 2001-05-05, 00:00 authored by Leonie Blackburn, Richard J. K. Taylor
Manganese dioxide is employed as an in situ oxidant for the one-pot conversion of alcohols into imines. In combination with polymer-supported cyanoborohydride (PSCBH), a one-pot oxidation−imine formation−reduction sequence is reported. This procedure enables alcohols to be converted directly into both secondary and tertiary amines.