posted on 2023-07-07, 05:29authored byMaximilian P. Born, Catrina Brüll, Holger Schüttrumpf
Littered plastics
are partly introduced into water bodies, ultimately
transporting this waste to the shores and oceans. At the shore, ultraviolet
(UV) radiation (also present in other environmental compartments)
and wave breaking cause plastics to degrade and fragment into smaller
particles, called microplastics, if below 5 mm. Since these plastics’
surfaces can act as vectors for hydrophobic (toxic) chemical substances
(e.g., per- and polyfluoroalkyl substances (PFAS)) and leach (toxic)
chemicals into the water, the increase in the surface area through
the fragmentation of plastics becomes relevant. Studies investigating
different effects on the fragmentation of plastics have mostly disregarded
a sufficient mechanical component for fragmentation, focusing on degradation
by UV radiation. Therefore, this study investigated the impact of
the mechanical fragmentation drivers, wave impact, and sediment abrasion
on the fragmentation of expanded polystyrene (EPS), high-density polyethylene
(PE-HD), and polyethylene terephthalate (PET) particles. In a newly
designed test facility called Slosh-Box, the mentioned impacts were
investigated concurrently. The results reveal that the mechanical
impacts alone are sufficient for plastic fragmentation, and the test
facility is suitable for fragmentation investigations. Furthermore,
the increase in surface area was determined via scanning electron
microscopy. For EPS, the surface area increased more than 2370-fold,
while for PE-HD and PET, surface areas increased between 1 and 8.6
times. Concluding from the results, the new test facility is suitable
for plastic fragmentation studies. In addition, sediment was revealed
to be a relevant fragmentation driver, which should be included in
every experiment investigating the fragmentation of plastic in a nearshore
environment independent of other drivers like UV radiation.