posted on 2022-01-03, 18:08authored byZhe Yang, Yu Ning, Chang He, Yumei Li, Sen Yang, Baoguo Yang, Jiawei Kang, Rainer Dähn, Yilian Li
The
fate of Cr(VI) in soils/sediments largely depends on its sorption
by iron oxides/hydroxides. But, their combination with surrounding
minerals (e.g., quartz (Qu), clays) evidently changes some properties.
Since ferrihydrite (Fh) is the precursor for most iron oxides, the
10 days sorption experiments studying Cr(VI) mobility were performed
using the reference Qu–montmorillonite (Mt)–Fh system.
From the results of batch experiment, ζ potential, Fourier transform
infrared spectroscopy, X-ray diffraction, and scanning electron microscopy
equipped with energy dispersive X-ray spectroscopy, chromium(VI) sorption
mechanisms are sensitive in Qu–Mt–Fh mixtures and closely
relate to pHs. At acidic conditions, the deposition of Fh on Qu/Mt
surfaces decreases the sorption sites for Cr(VI) while the formation
of outer-sphere complexation driven by electrostatic attraction increases
Cr(VI) mobility in contrast to inner-sphere complexation. At alkaline
conditions, the situations are different in Qu–Fh and Mt–Fh
systems, even though both increase sorption compared to that with
only Fh. Sorption is subject to free Fh in Qu–Fh mixtures,
while considering the high loading of the Mt–Fh surface due
to the strong association of Si–OH with Fe–O(H), CrO42– captures are favorable by hydrogen bonding
with water as outer-sphere complexation in Mt–Fh mixtures,
resulting in high mobility especially at Mt/Fh ratios of 2/3.