jo500465m_si_001.pdf (3 MB)
Hypervalent Iodine Mediated Synthesis of C‑2 Deoxy Glycosides and Amino Acid Glycoconjugates
journal contribution
posted on 2014-05-16, 00:00 authored by Maidul Islam, Nishanth D. Tirukoti, Shyamapada Nandi, Srinivas HothaA simple, efficient,
and practical method for the synthesis of C-2 deoxy-2-iodo glycoconjugates in self-assembled
structures was found using PhI(OCOR)2. 2-Iodo glycoserinyl
esters were intramolecularly converted into 2-iodo serinyl glycosides
which upon dehalogenation gave C-2 deoxy amino acid glycoconjugates.