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How an Enzyme Might Accelerate an Intramolecular Diels−Alder Reaction: Theozymes for the Formation of Salvileucalin B

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journal contribution
posted on 19.03.2010, 00:00 by Dean J. Tantillo
Quantum chemical calculations reveal how functional group arrays present in known enzyme active sites could accelerate an intramolecular Diels−Alder reaction proposed to occur during the biosynthesis of a complex terpenoid natural product.

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