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Highly Luminescent SmIII Complexes with Intraligand Charge-Transfer Sensitization and the Effect of Solvent Polarity on Their Luminescent Properties

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journal contribution
posted on 20.04.2015, 00:00 by Wai-Sum Lo, Junhui Zhang, Wing-Tak Wong, Ga-Lai Law
Samarium complexes with the highest quantum yields to date have been synthesized, and their luminescence properties were studied in 12 solvents. Sensitization via a nontriplet intraligand charge-transfer pathway was also successfully demonstrated in solution states with good quantum yields.