High Thermoelectric Properties of n‑Type AgBiSe₂

We report on the thermoelectric (TE) performance of intrinsic n-type AgBiSe₂, a Pb-free material with more earth-abundant and cheaper elements than intrinsic p-type homologous AgSbTe₂. Pb doping changes n-type AgBiSe₂ to p-type but leads to poor electrical transport properties. Nb doping enhances the TE properties of n-type AgBiSe₂ by increasing the carrier concentration. As a result of the intrinsically low thermal conductivity (0.7 W m^–1 K^–1), low electrical resistivity (5.2 mΩ cm), and high absolute Seebeck coefficient (−218 μV/K), the TE figure of merit (ZT) at 773 K is significantly increased from 0.5 for solid-state-synthesized pristine AgBiSe₂ to 1 for Ag_0.96Nb_0.04BiSe₂, which makes it a promising n-type candidate for medium-temperature TE applications.