High-Temperature Synthesis of Small-Sized Pt/Nb Alloy Catalysts on Carbon Supports for Hydrothermal Reactions
journal contributionposted on 21.10.2020, 18:34 by Shi-Long Xu, Shan-Cheng Shen, Wei Xiong, Shuai Zhao, Lu-Jie Zuo, Lei Wang, Wei-Jie Zeng, Sheng-Qi Chu, Ping Chen, Yue Lin, Kun Qian, Weixin Huang, Hai-Wei Liang
Catalytic biomass conversions are sustainable processes to produce value-added fuels and chemicals but need stable catalysts that can tolerate harsh hydrothermal conditions. Herein, we report a hydrothermally stable catalyst by alloying Pt with a high-melting-point metal Nb. The Pt/Nb alloy catalysts are prepared by H2 reduction at a high temperature of 900 °C with a high-surface-area carbon black support, which can suppress metal sintering at high temperatures and thus lead to small-sized alloyed Pt/Nb particles of only 2.2 nm. Taking the advantages of surface acid property provided by the Nb sites and the size effect, the prepared C-supported small-sized Pt/Nb alloy catalysts exhibit attractive activities for the hydrogenation of levulinic acid into γ-valerolactone and the water–gas shift reaction. More significantly, benefiting from the inherent stability of high-melting-point Nb, the Pt/Nb alloy catalysts show much enhanced hydrothermal stability compared to commercial Pt/C and Ru/C catalysts.
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γ- valerolactonehydrothermal conditionsH 2 reductionNb sites2.2 nmlevulinic acidsurface acid propertyHydrothermal Reactions Catalytic bi...High-Temperature Synthesishigh-surface-area carbonmetal sinteringhigh-melting-point metal Nbhydrothermal stabilityalloying Ptsize effectcatalysthigh-melting-point Nb