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Hierarchical Configuration of NiCo2S4 Nanotube@Ni–Mn Layered Double Hydroxide Arrays/Three-Dimensional Graphene Sponge as Electrode Materials for High-Capacitance Supercapacitors
journal contribution
posted on 2015-07-29, 00:00 authored by Houzhao Wan, Jia Liu, Yunjun Ruan, Lin Lv, Lu Peng, Xiao Ji, Ling Miao, Jianjun JiangThree
dimensional (3D) hierarchical network configurations are
composed of NiCo2S4 nanotube @Ni–Mn layered
double hydroxide (LDH) arrays in situ grown on graphene sponge. The
3D graphene sponge with robust hierarchical porosity suitable for
as a basal growth has been obtained from a colloidal dispersion of
graphene oxide using a simple directional freeze-drying technique.
The high conductive NiCo2S4 nanotube arrays
grown on 3D graphene shows excellent pseudocapacity and good conductive
support for high-performance Ni–Mn LDH. The 3D NiCo2S4@Ni–Mn LDH/GS shows a high specific capacitance
(Csp) 1740 mF cm–2 at
1 mA cm–2, even at 10 mA cm–2,
1267.9 mF cm–2 maintained. This high-performance
composite electrode proposes a new and feasible general pathway as
3D electrode configuration for energy storage devices.