American Chemical Society
ol702183d_si_002.pdf (2.84 MB)

Helical Chirality Transmission through a p-Phenylene Fragment in a Hexa-λ5-phosphazene

Download (2.84 MB)
journal contribution
posted on 2007-10-25, 00:00 authored by Mateo Alajarín, Carmen López-Leonardo, José Berná
The helical chirality of a conformationally stable macrobicyclic tri-λ5-phosphazene is propagated through to its C3 symmetry axis and causes a measurable stereoinduction in the formation process of a second macrobicyclic tri-λ5-phosphazene unit connected to the former one by a p-phenylene linker.