Helical Chirality Transmission through a
p-Phenylene Fragment in a
Hexa-λ5-phosphazene

Alajarín, Mateo; López-Leonardo, Carmen; Berná, José

doi:10.1021/ol702183d.s002

ol702183d_si_002.pdf (2.84 MB)

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Helical Chirality Transmission through a p-Phenylene Fragment in a Hexa-λ⁵-phosphazene

journal contribution

posted on 2007-10-25, 00:00 authored by Mateo Alajarín, Carmen López-Leonardo, José Berná

The helical chirality of a conformationally stable macrobicyclic tri-λ⁵-phosphazene is propagated through to its C₃ symmetry axis and causes a measurable stereoinduction in the formation process of a second macrobicyclic tri-λ⁵-phosphazene unit connected to the former one by a p-phenylene linker.