posted on 2021-08-09, 16:10authored byZhi-Guo Wang, Xin Wei, Meng-Han Bai, Jun Lei, Ling Xu, Hua-Dong Huang, Jiguang Du, Kun Dai, Jia-Zhuang Xu, Zhong-Ming Li
Hexagon
boron nitride (BN) has evolved into a quite competitive
building block in electrical and electronic fields. However, exfoliation
and functionalization of BN nanosheets (BNNSs) confront a formidable
challenge. Herein, an effective and green saccharide-assisted mechanochemical
approach was proposed to exfoliate and synchronously functionalize
BNNSs. The production yield of BNNSs exhibited a notable enhancement
by incorporating saccharides, where the highest yield was up to ∼29.4%
with the assistance of glucose. The saccharides enhanced the applied
force of ball milling to promote BN delamination. The exfoliated cost
is much lower for our proposed approach than for the previously reported
exfoliation methods. The theoretical first-principle calculation and
experimental results confirmed that the obtained BNNSs (saccharide-g-BNNSs) remained intact and were covalently grafted with
saccharides in different degrees. Benefitting from the outstanding
comprehensive properties of saccharide-g-BNNSs, their
gelatin composite films exhibited multifunctional performance, such
as high/anisotropic thermal conductivity, shielding deep blue to the
UV light, and flame retardance. Our work paves a promising way to
greenly prepare few-layered and functionalized BNNSs and to expedite
their applications.