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Gas Sorption, Second-Order Nonlinear Optics, and Luminescence Properties of a Multifunctional srs-Type Metal–Organic Framework Built by Tris(4-carboxylphenylduryl)amine

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journal contribution
posted on 06.07.2015, 00:00 authored by Yan-Ping He, Yan-Xi Tan, Jian Zhang
A chiral 8-fold interpenetrating srs-type metal–organic framework FIR-28 (FIR denotes Fujian Institute of Research) exhibits a surface area of 1029 m2/g and high C3H8/CH4 separation capacity in excess of 154 and displays strong powder second-harmonic-generation efficiency, with more than half over potassium dihydrogen phosphate powder. Moreover, the luminescence properties of FIR-28 are dependent on the solvent guests.