posted on 2021-04-02, 18:35authored byWeigang Lu, Blake Birmingham, Dmitri V. Voronine, Drew Stolpman, Sharad Ambardar, Deniz Altunoz Erdogan, Emrah Ozensoy, Zhenrong Zhang, Touradj Solouki
Al
nanostructures have unique optical properties such as widely
tunable surface plasmon resonances from deep UV to NIR that can be
used for label-free fluorescence enhancement and surface-enhanced
Raman scattering. Various Al nanostructures have been fabricated using
sophisticated “top-down” lithographic and “bottom-up”
colloidal methods. Here, we developed a simple and efficient method
of synthesizing two-dimensional (2D) aluminum (Al) nanocrystals from
commercially available Al foil using ultrasonic exfoliation under
ambient environment. 2D Al nanocrystals with sizes from a few hundred
nanometers to several micrometers and thickness in the tens of nanometers
were isolated through centrifugation separation. The exfoliated 2D
Al nanocrystals are covered with a passivated Al2O3 nanolayer. The determined exfoliation mechanism is a combination
of the preferred cleavage along the (111) surface planes and layer-by-layer
Al2O3 exfoliation from the surface of the 2D
Al nanocrystals. We demonstrate that the 2D Al nanocrystals can be
assembled at water/air interface and transferred to different substrates
to form 2D Al nanocrystal films. These 2D Al nanocrystal films exhibit
surface plasmon resonance in the visible spectral range and show enhanced
Raman signals of adenine using a 532 nm excitation. These 2D Al nanocrystal
films could be further developed for new optical and sensing applications.