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First Tandem Free-Radical Cyclization Reaction of Alkylenecyclopropanes:  A Novel and Efficient Method for the Preparation of 2-(3,4-Dihydronaphthalen-2-yl)malonic Acid Diethyl Esters

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journal contribution
posted on 06.08.2004, 00:00 by Hongwei Zhou, Xian Huang, Wanli Chen
Alkylidenecyclopropanes undergo Mn(OAc)3-mediated addition with malonate, leading to dihydronaphthalene derivatives in moderate yields.