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First Structurally Authenticated Heavier Alkali Metal Phosphinomethanide

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journal contribution
posted on 03.07.1999, 00:00 by William Clegg, Keith Izod, Paul O'Shaughnessy
Metathesis between Li[C(SiMe3)2{P(C6H4-2-CH2NMe2)2}] (1) and KO-t-Bu yields [{K[C(SiMe3)2{P(C6H4-2-CH2NMe2)2}]}2] (2), the first heavier alkali metal complex of a phosphorus-stabilized carbanion to be structurally characterized.

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