First Metal Azide Complex with Isonicotinate as a Bridging Ligand
Showing New Net Topology:  Hydrothermal Synthesis, Structure, and
Magnetic Properties

Liu, Fu-Chen; Zeng, Yong-Fei; , Jiao; Bu, Xian-He; Ribas, Joan; Batten, Stuart R.

doi:10.1021/ic051896h.s002

ic051896h_si_002.pdf (428.06 kB)

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First Metal Azide Complex with Isonicotinate as a Bridging Ligand Showing New Net Topology: Hydrothermal Synthesis, Structure, and Magnetic Properties

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posted on 03.04.2006, 00:00 by Fu-Chen Liu, Yong-Fei Zeng, Jiao, Xian-He Bu, Joan Ribas, Stuart R. Batten

A new 3D azido-bridged coordination polymer, [Co_1.5(N₃)(OH)(Isonic)]_n (1), has been synthesized and characterized and its magnetic properties studied. Isonicotinate acts as a bridging coligand in this complex. In 1, all of the ligands take tridentate bridging coordination modes, and the overall structure of 1 exhibits a new 3,6-connected net topology.

First Metal Azide Complex with Isonicotinate as a Bridging Ligand Showing New Net Topology: Hydrothermal Synthesis, Structure, and Magnetic Properties

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