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Ferromagnetic Ordering and Metamagnetism in Malonate Bridged 3D Diamond-like and Honeycomb-like Networks:  [Cu(mal)(DMF)]n and {[Cu(mal)(0.5pyz)]·H2O}n (mal = Malonate Dianion, DMF = N,N-dimethylformamide, pyz = Pyrazine)

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journal contribution
posted on 25.06.2003, 00:00 by Tian-Fu Liu, Hao-Ling Sun, Song Gao, Shi-Wei Zhang, Tai-Chu Lau
Two three-dimensional (3D) malonate bridged networks, [Cu(mal)(DMF)]n (1) and {[Cu(mal)(0.5pyz)]·H2O}n (2), have been synthesized in H2O−DMF solution. Compound 1 exhibits ferromagnetic ordering below 2.6 K (Tc), and 2 displays a metamagnetic behavior below 3.2 K (TN).