Ferroelectricity and Ferromagnetism Achieved via Adjusting Dimensionality in BiFeO₃/BiMnO₃ Superlattices

Integrating characteristics of materials through constructing artificial superlattices (SLs) has raised extensive attention in multifunctional materials. Here, we report the synthesis of BiFeO₃/BiMnO₃ SLs with considerable ferroelectric polarizations and tunable magnetic moments. The polarization of BiFeO₃/BiMnO₃ SLs presents a decent value of 12 μC/cm², even as the dimensionality of BiFeO₃ layers per period is reduced to about five-unit cells when keeping the BiMnO₃ layers same. Moreover, it is found that the tunable magnetic moments of SLs are linked intimately to the dimensionality of BiFeO₃ layers. Our simulations demonstrate that the superexchange interaction of Fe–O–Mn tends to be antiferromagnetic (AFM) with a lower magnetic domain formation energy rather than ferromagnetic (FM). Therefore, as the dimensionality of BiFeO₃ per period is reduced, the AFM superexchange interaction between BiFeO₃ and BiMnO₃ in the SLs becomes weak, promoting a robust magnetization. This interlayer modulation effect in SLs presents an alluring way to accurately control the multiple order parameters in a multiferroic oxide system.