Ether–Water Hybrid Electrolyte Contributing to Excellent Mg Ion Storage in Layered Sodium Vanadate

Magnesium ion batteries have potential for large-scale energy storage. However, the high charge density of Mg²⁺ ions establishes a strong intercalation energy barrier in host materials, causing sluggish diffusion kinetics and structural degradation. Here, we report that the kinetic and dissolution issues connected to cathode materials can be resolved simultaneously using a tetraethylene glycol dimethyl ether (TEGDME)–water hybrid electrolyte. The lubricating and shielding effect of water solvent could boost the swift transport of Mg²⁺, contributing to a high diffusion coefficient within the sodium vanadate (NaV₈O₂₀·nH₂O) cathode. Meanwhile, the organic TEGDME component can coordinate with water to diminish its activity, thus providing the hybrid electrolyte with a broad electrochemical window of 3.9 V. More importantly, the TEGDME preferentially amassed at the interface, leading to a robust cathode electrolyte interface layer that suppresses the dissolution of vanadium species. Consequently, the NaV₈O₂₀·nH₂O cathode achieved a specific capacity of 351 mAh g^–1 at 0.3 A g^–1 and a long cycle life of 1000 cycles in this hybrid electrolyte. A mechanism study revealed the reversible interaction of Mg²⁺ during cycles. This organic water hybrid electrolyte is effective for overcoming the difficulty of multivalent ion storage.