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Enantioselective Total Synthesis of Plectosphaeroic Acid B

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journal contribution
posted on 19.02.2016, 16:51 by Salman Y. Jabri, Larry E. Overman
The first total synthesis of a member of the plectosphaeroic acid family of fungal natural products is reported. Key steps include the late-stage formation of the hindered N6–C9″ bond and stereoselective introduction of the two methylthio substituents.