jo301532t_si_001.pdf (3.33 MB)

Enantioselective Hydrogenation of β‑Ketophosphonates with Chiral Ru(II) Catalysts

Download (3.33 MB)
journal contribution
posted on 05.10.2012, 00:00 by Xiaoming Tao, Wanfang Li, Xin Ma, Xiaoming Li, Weizheng Fan, Lvfeng Zhu, Xiaomin Xie, Zhaoguo Zhang
Highly effective asymmetric hydrogenation of β-ketophosphonates in the presence of Ru–(S)-SunPhos as catalyst was realized; good to excellent enantioselectivities (up to 99.9% ee) and excellent diastereoselectivities (96:4) were obtained.

History

Exports