Enantio- and Diastereoselective
Reductive Aldol Reactions with
Iridium-Pybox Catalysts

Zhao, Cun-Xiang; Duffey, Matthew O.; Taylor, Steven J.; Morken, James P.

doi:10.1021/ol015859f.s001

Enantio- and Diastereoselective Reductive Aldol Reactions with Iridium-Pybox Catalysts

journal contribution

posted on 2001-05-12, 00:00 authored by Cun-Xiang Zhao, Matthew O. Duffey, Steven J. Taylor, James P. Morken

A catalytic amount of [(cod)IrCl]₂ and indane-pybox converts diethylmethylsilane, methyl acrylate, and certain aldehydes to the derived reductive aldol adduct with good enantio- and diastereocontrol.

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Enantio methyl acrylate diastereocontrol enantio reductive aldol adduct Catalyst aldehyde convert diethylmethylsilane Diastereoselective Reductive Aldol Reactions

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Enantio- and Diastereoselective Reductive Aldol Reactions with Iridium-Pybox Catalysts

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