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Electronic Structure Determination of Pyridine N‑Heterocyclic Carbene Iron Dinitrogen Complexes and Neutral Ligand Derivatives

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journal contribution
posted on 17.12.2015, 05:07 by Jonathan M. Darmon, Renyuan Pony Yu, Scott P. Semproni, Zoë R. Turner, S. Chantal E. Stieber, Serena DeBeer, Paul J. Chirik
The electronic structures of pyridine N-heterocyclic dicarbene (iPrCNC) iron complexes have been studied by a combination of spectroscopic and computational methods. The goal of these studies was to determine if this chelate engages in radical chemistry in reduced base metal compounds. The iron dinitrogen example (iPrCNC)­Fe­(N2)2 and the related pyridine derivative (iPrCNC)­Fe­(DMAP)­(N2) were studied by NMR, Mössbauer, and X-ray absorption spectroscopy and are best described as redox non-innocent compounds with the iPrCNC chelate functioning as a classical π acceptor and the iron being viewed as a hybrid between low-spin Fe(0) and Fe­(II) oxidation states. This electronic description has been supported by spectroscopic data and DFT calculations. Addition of N,N-diallyl-tert-butylamine to (iPrCNC)­Fe­(N2)2 yielded the corresponding iron diene complex. Elucidation of the electronic structure again revealed the CNC chelate acting as a π acceptor with no evidence for ligand-centered radicals. This ground state is in contrast with the case for the analogous bis­(imino)­pyridine iron complexes and may account for the lack of catalytic [2π + 2π] cycloaddition reactivity.